Chemical Reactions of Haloalkanes

What is the order of reactivity of following compounds towards  $S_N{}^1$ substitutions reaction.
(i) 

(ii) 

(iii) 

What is the order of reactivity of following compounds towards  ${\mathrm{S}}_{\mathrm{N}}1$ substitution reaction.

Which one of the following two substances undergoes ${\mathrm{S}}_{\mathrm{N}}1$ reaction faster?

(i)    or   (ii) 

An S_N2 reaction at an asymmetric carbon of a compound always gives:

A solution of (+) -2-chloro-2-phenylethane in toluene racemises slowly in the presence of small amount of  $SbC{l}_5$ , due to the formation of –

A solution of (+) -2-chloro-1-phenylethane in toluene racemises slowly in the presence of small amount of  ${\mathrm{SbCl}}_5$, due to the formation of:

n–propyl bromide on treatment with ethanolic potassium hydroxide produces

The major product of the following reaction is

The product of following reaction is –

${\text{C}}_2{\text{H}}_5{\text{O}}^{-}+\text{C}{\text{H}}_3\text{C}{\text{H}}_2\text{I}\to$

In the reaction, ${\mathrm{CH}}_3\mathrm{Br} \stackrel{\mathrm{KCN}}{⟶} \mathrm{A} \stackrel{{\mathrm{H}}^{+}}{\to } \mathrm{B} \stackrel{{\mathrm{LiAlH}}_4}{⟶} \mathrm{C}$

The product C is.

Treatment of $2-\mathrm{bromo}-2-\mathrm{methylbutane}$ with sodium ethoxide in ethanol at $70°\mathrm{C}$ gives a mixture of two products ${\mathrm{X}}_1$ and ${\mathrm{X}}_2$ through one step processes. The energy profile diagrams of the two processes are shown below.

 An alkyl halide with $\beta$-hydrogen atom, when treated with a nucleophile/base, undergoes a substitution reaction or an climination reaction, depending on the strength and size of the nucleophile base and the reaction conditions.

 
For the above reaction, the correct statement(s) is(are):

The correct order for the hydrolysis in $50\%$ aqueous ethanol is

In the following question a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.

Assertion: $\mathrm{KCN}$ reacts with methyl chloride to give methyl isocyanide.
Reason: ${\mathrm{CN}}^{–}$ is an ambident nucleophile.

Saytzeff's rule states that _____ product is the major product in dehydrohalogenation of an alkyl halide.

Which of the following best describes Saytzeff's rule?